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By Rudi van Eldik, Jan Reedijk

Advances in Inorganic Chemistry quantity fifty eight makes a speciality of homogeneous biomimetic oxidation catalysis. Contributions through major specialists within the box disguise very important advances in inorganic and bioinorganic chemistry. Contributions contain diversity-based methods to selective biomimetic oxidation catalysis; the selective conversion of hydrocarbons with H2O2 utilizing biomimetic non-heme iron and manganese oxidation catalysis; DNA oxidation by means of copper and manganese complexes; impacts of the ligand in copper-dioxygen complex-formation and substrate oxidations; biomimetic oxidations via dinuclear and trinuclear copper complexes. within the ultimate contribution the authors specialize in eco-friendly oxidation of alcohols utilizing biomimetic copper complexes and enzymes as catalysts. quantity fifty eight offers one other welcomed addition to the generally acclaimed sequence, Advances in Inorganic Chemistry. * comprises new details at the vital advances in inorganic and bioinorganic chemistry * every one bankruptcy is totally referenced * comprises complete reports written through major specialists within the box. learn more... content material: hide -- Advances in INORGANIC CHEMISTRY -- Contents -- Preface -- Diversity-Based techniques to Selective Biomimetic Oxidation Catalysis -- advent -- Biomimetic Oxidation Catalysis in response to steel Complexes -- Biomimetic Oxidation Catalysis in line with in basic terms natural Catalysts -- Directed Evolution of Enzymes for Oxidation Catalysis -- Epilogue -- Acknowledgments -- References -- Selective Conversion of Hydrocarbons with H2O2 utilizing Biomimetic Non-heme Iron and Manganese Oxidation Catalysts -- normal advent -- organic Enzymes and Catalytic Oxidation -- Biomimetic Iron Catalysts -- Biomimetic Manganese Catalysts -- Concluding comments -- Acknowledgments -- References -- DNA Oxidation by way of Copper and Manganese Complexes -- advent -- Oxidative DNA Cleavage through Copper Complexes -- Oxidative DNA harm via Manganese Complexes -- end -- Abbreviations -- Acknowledgments -- References -- Ligand impacts in Copper-Dioxygen Complex-Formation and Substrate Oxidations -- advent -- Tetradentate Ligand affects -- Tridentate Ligand impacts: Side-on Peroxo vs. Bis(u-oxo) Equilibrium -- Ligand results at the Exogenous Substrate Reactivity of Cu2O2 Compounds -- precis and Outlook -- References -- Biomimetic Oxidations via Dinuclear and Trinuclear Copper Complexes -- Copper Proteins Containing Dinuclear and Trinuclear steel Clusters -- Biomimetic Oxidations via Dinuclear Complexes as Tyrosinase and Catechol Oxidase types: basic features -- Phenolase task -- Catecholase job -- Oxidations by means of Trinuclear Complexes -- Conclusions -- Acknowledgments -- References -- eco-friendly oxidation of alcohols utilizing biomimetic Cu complexes and Cu enzymes as catalysts -- advent -- Enzymatic platforms utilizing Cu-oxidases -- Biomimetic platforms for Alcohol Oxidation -- destiny Outlook -- References -- Index -- Contents of prior Volumes -- final web page. summary: Advances in Inorganic Chemistry quantity fifty eight makes a speciality of homogeneous biomimetic oxidation catalysis. Contributions by way of prime specialists within the box disguise very important advances in inorganic and bioinorganic chemistry. Contributions contain diversity-based ways to selective biomimetic oxidation catalysis; the selective conversion of hydrocarbons with H2O2 utilizing biomimetic non-heme iron and manganese oxidation catalysis; DNA oxidation by way of copper and manganese complexes; affects of the ligand in copper-dioxygen complex-formation and substrate oxidations; biomimetic oxidations via dinuclear and trinuclear copper complexes. within the ultimate contribution the authors specialise in eco-friendly oxidation of alcohols utilizing biomimetic copper complexes and enzymes as catalysts. quantity fifty eight offers one other welcomed addition to the commonly acclaimed sequence, Advances in Inorganic Chemistry. * contains new info at the very important advances in inorganic and bioinorganic chemistry * every one bankruptcy is totally referenced * comprises finished reports written by way of major specialists within the box

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Biomimetic manganese catalysts A. Alkane oxidation B. Olefin epoxidations C. cis-Dihydroxylation V. Concluding remarks Acknowledgments References 29 31 31 31 34 37 37 37 49 53 54 55 55 56 66 68 69 70 I. General Introduction Oxidation is one of the most important industrial reactions. In the past decades, impressive progress has been made in the development of oxidation catalysis, resulting in many novel industrial technologies. Oxidation catalysis is particularly an important technological area that lies at the heart of a variety of processes for producing bulk and ¢ne chemicals and for eliminating pollution.

5 $ 10 (88) (85) (85) (85) (91) (88) (85) (97) FIG. 15. Non-heme iron complexes as models for naphthalene 1,2-dioxygenase (88). hexacoordinate metal complexes with two labile ligands on the iron(II) center; upon treatment with H2O2 a conversion to the iron(III) active form is observed. Depending on whether these labile sites are located cis or trans to each other, di¡erent types of selectivity can be observed. Complexes with trans-open coordination sites (Fig. 15) like [Fe(cyclam)(CH3CN)2](OTf)2 (91) and [Fe(bph)(CH3CN)2](ClO4)2 (88), catalyze the epoxidation of ole¢ns with H2O2 as terminal oxidant.

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